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Zinc-catalyzed enantioselective hydrosilylation of imines
- Issue Date
- Jun-2006
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- enantioselectivity; hydrosilylation; imine; ligands; zinc
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, v.348, no.9, pp.1029 - 1032
- Indexed
- SCIE
SCOPUS
- Journal Title
- ADVANCED SYNTHESIS & CATALYSIS
- Volume
- 348
- Number
- 9
- Start Page
- 1029
- End Page
- 1032
- ISSN
- 1615-4150
- Abstract
- The highly enantioselective reduction of imines is achieved by employing chiral Zn/diamine catalysts. This new catalytic protocol offers attractive features such as use of a non-precious metal and an inexpensive silane, easy modification of chiral diamine ligands and provides ready access to chiral amines in good yields and with excellent enantioselectivities.
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