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Surface passivation of crystalline silicon wafer using h2 s gasopen access

Authors
Lin, J.[Lin, J.]Jee, H.[Jee, H.]Yoo, J.[Yoo, J.]Yi, J.[Yi, J.]Jeong, C.[Jeong, C.]Lee, J.[Lee, J.]
Issue Date
Apr-2021
Publisher
MDPI AG
Keywords
Crystalline silicon; Dangling bonds; H2 S; Minority carrier lifetime; Passivation
Citation
Applied Sciences (Switzerland), v.11, no.8
Indexed
SCIE
SCOPUS
Journal Title
Applied Sciences (Switzerland)
Volume
11
Number
8
URI
https://scholarworks.bwise.kr/skku/handle/2021.sw.skku/90097
DOI
10.3390/app11083527
ISSN
2076-3417
Abstract
We report the effects of H2 S passivation on the effective minority carrier lifetime of crystalline silicon (c-Si) wafers. c-Si wafers were thermally annealed under an H2 S atmosphere at various temperatures. The initial minority carrier lifetime (6.97 µs) of a c-Si wafer without any passivation treatments was also measured for comparison. The highest minority carrier lifetime gain of 2030% was observed at an annealing temperature of 600◦ C. The X-ray photoelectron spectroscopy analysis revealed that S atoms were bonded to Si atoms after H2 S annealing treatment. This indicates that the increase in minority carrier lifetime originating from the effect of sulfur passivation on the silicon wafer surface involves dangling bonds. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
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