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Synthesis and Properties of Pentafluorosulfanyl Group (SF5)-Containing Meta-Diamide Insecticidesopen access
- Authors
- Kim, JG[Kim, Jae Gon]; Kang, OY[Kang, On-Yu]; Kim, SM[Kim, Sang Mee]; Issabayeva, G[Issabayeva, Guldana]; Oh, IS[Oh, In Seok]; Lee, Y[Lee, Yaeji]; Lee, WH[Lee, Won Hyung]; Lim, HJ[Lim, Hwan Jung]; Park, SJ[Park, Seong Jun]
- Issue Date
- Dec-2020
- Publisher
- MDPI
- Keywords
- meta-diamide; pentafluorosulfanyl; insecticide; GABARs
- Citation
- MOLECULES, v.25, no.23
- Indexed
- SCIE
SCOPUS
- Journal Title
- MOLECULES
- Volume
- 25
- Number
- 23
- ISSN
- 1420-3049
- Abstract
- Herein, we describe novel pentafluorosulfanyl (SF5) group-containing meta-diamide insecticides. For the facile preparation of the SF5-based compounds 4a-d, practical synthetic methods were applied. Among newly synthesized compounds, 3-benzamido-N-(2,6-dimethyl-4-(pentafluoro-lambda(6)-sulfanyl)phenyl)-2-fluorobenzamide 4d showed (i) a high insecticidal activity, (ii) an excellent selectivity to insects, and (iii) good levels of water solubility and log P values. In this study, we demonstrated that the pentafluorosulfanyl moiety could serve as an attractive functionality for the discovery of a new scope of crop-protecting agents.
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