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V2Se: a novel antifluorite-type cubic phase with a metal-metal bonding
- Issue Date
- Jun-2019
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- DALTON TRANSACTIONS, v.48, no.24, pp.8556 - 8559
- Indexed
- SCIE
SCOPUS
- Journal Title
- DALTON TRANSACTIONS
- Volume
- 48
- Number
- 24
- Start Page
- 8556
- End Page
- 8559
- ISSN
- 1477-9226
- Abstract
- A new antifluorite-type (Li2O-type) cubic compound, V2Se, has been synthesized for the first time by changing the amount of selenium in chemical vapor transport. The vanadium-based cubic phase studied here reveals a metal-metal bonding feature in the electronic band structure. This compound is the first example of an antifluorite-type cubic structure in a V-Se system.
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