Poly[bis(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato- κ4 O 1:O 1′:O 4:O 4′)bis(tetrahydrofuran-κO)dizinc]
- Authors
- Choi, S.B.; Jhon, Y.H.; Ko, N.; Yang, J.K.
- Issue Date
- 2014
- Citation
- Acta Crystallographica Section E: Structure Reports Online, v.70, no.1
- Journal Title
- Acta Crystallographica Section E: Structure Reports Online
- Volume
- 70
- Number
- 1
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/10990
- DOI
- 10.1107/S1600536813031887
- ISSN
- 1600-5368
- Abstract
- The title compound, [Zn2(C8F4O 4)2(C4H8O)2] n, has a three-dimensional metal-organic framework structure. The asymmetric unit consists of two ZnII atoms, two tetrahydrofuran ligands, one 2,3,5,6-tetrafluorobenzene-1,4-dicarboxylate ligand and two half 2,3,5,6-tetrafluorobenzene-1,4-dicarboxylate ligands, which are completed by inversion symmetry. One ZnII atom has a distorted trigonal-bipyramidal coordination geometry, while the other has a distorted octahedral geometry. Two independent tetrahydrofuran ligands are each disordered over two sets of sites with occupancy ratios of 0.48(4):0.52(4) and 0.469(17):0.531(17).
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