Detailed Information
Cited 1 time in 
Cited 2 time in 
Cited 2 time in
Metadata Downloads
Methanol-mediated benzimidazolamidocavitand
- Authors
- Park, Yeon Sil; Paek, Kyungsoo
- Issue Date
- 20-Nov-2013
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Cavitand; Benzimidazolamido moiety; Methanol-mediated hydrogen bonding; CH/pi interaction; Resorcin[4]arene
- Citation
- TETRAHEDRON LETTERS, v.54, no.47, pp.6291 - 6295
- Journal Title
- TETRAHEDRON LETTERS
- Volume
- 54
- Number
- 47
- Start Page
- 6291
- End Page
- 6295
- ISSN
- 0040-4039
- Abstract
- Resorcin[4]arene-based cavitand bearing four benzimidazolamido moieties on the upper rim has vase conformation by the clip-type hydrogen bonds of a methanol with C=O as well as -NH of a benzimidazolamido unit. These methanol-mediated rigidifications of four benzimidazolamido moieties result in a narrow and deep cavity, and the aromatic protons in the -NH side of benzimidazolyl unit direct to adjacent benzimidazolyl unit. This methanol-mediated cavitand forms weak complexes of n-alkanes by CH/pi interaction with the aromatic it surfaces of the walls at low temperature. (C) 2013 Elsevier Ltd. All rights reserved.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
Related Researcher
- Paek, Kyung soo
- College of Natural Sciences (Department of Chemistry)