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Core-shell nanostructure supported Pt catalyst with improved electrocatalytic stability in oxygen reduction reaction

Authors
Kim, Do-YoungHan, Sang-BeomLee, Young-WooPark, Kyung-Won
Issue Date
15-Jan-2013
Publisher
ELSEVIER SCIENCE SA
Keywords
Composite materials; Nanostructures; Electrochemical properties; Electrochemical techniques
Citation
MATERIALS CHEMISTRY AND PHYSICS, v.137, no.3, pp.704 - 708
Journal Title
MATERIALS CHEMISTRY AND PHYSICS
Volume
137
Number
3
Start Page
704
End Page
708
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/11373
DOI
10.1016/j.matchemphys.2012.11.006
ISSN
0254-0584
Abstract
Core-shell nanostructure electrode (TiO2@C) for oxygen reduction reaction is prepared with TiO2 nanoparticles at 900 degrees C in a methane atmosphere. The TiO2@C supported Pt catalyst (Pt/TiO2@C) contains Pt nanoparticles on TiO2@C nanostructure electrodes consisting of TiO2 as a core and carbon as a shell. In the accelerated stability test, the Pt/TiO2@C exhibits a superior ORR stability to conventional carbon supported Pt catalyst. It is likely that the enhanced catalytic properties of the nanostructure supported Pt catalyst may be due to graphite-like carbon and an improved electronic conductivity of the core shell nanostructure. (C) 2012 Elsevier B.V. All rights reserved.
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