설파디아진 은으로부터 항균 산성염료 및 분산염색용 항균 첨가제의 합성과 이들의 특성 분석Syntheses and Characterization of Antimicrobial Acid Dyes and Antimicrobial Additives for Disperse Dyeing from Silver Sulfadiazine
- Other Titles
- Syntheses and Characterization of Antimicrobial Acid Dyes and Antimicrobial Additives for Disperse Dyeing from Silver Sulfadiazine
- Authors
- 차희철; 김영호
- Issue Date
- Jun-2013
- Publisher
- 한국섬유공학회
- Keywords
- silver sulfadiazine; 8-amino-1-naphthol-3; 6-disulfonic acid (H-acid); coupling; acid dye; additives for disperse dyeing; antimicrobial activity; fastness
- Citation
- 한국섬유공학회지, v.50, no.3, pp.158 - 166
- Journal Title
- 한국섬유공학회지
- Volume
- 50
- Number
- 3
- Start Page
- 158
- End Page
- 166
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/11585
- DOI
- 10.12772/TSE.2013.50.158
- ISSN
- 1225-1089
- Abstract
- Two acid dyes having excellent antimicrobial activity were synthesized by using silver sulfadiazine, a wellknownantibiotic, and 8-amino-1-naphthol-3,6-disulfonic acid (H-acid). The diazonium salt of silver sulfadiazine (S1)and the acetylated H-acid (H1) were prepared first, and then an antimicrobial red acid dye (Acid-Red) was synthesizedvia a coupling reaction of S1 and H1. An antimicrobial blue acid dye (Acid-Blue) was also synthesized by the successivecoupling reactions of H-acid with the diazonium salt of aniline-2,5-disulfonic acid (B1) and the diazonium saltof sliver sulfadiazine (S1). Two colorless antimicrobial additives for disperse dyeing, Disperse-ES and Disperse-AS,were also synthesized by reacting silver sulfadiazine with diethyl sulfate and acetic anhydride, respectively. The synthesizedantimicrobial dyes and additives were characterized by Fourier transform infrared (FT-IR), UV-vis, and energydispersive X-ray (EDX) analyses. Although the nylon fabric dyed with either Acid-Red or Acid-Blue showed poor lightfastness, it had good washing and crocking fastness. The nylon fabrics dyed with Acid-Red and Acid-Blue and polyethyleneterephthalate (PET) fabrics treated with Disperse-ES or Disperse-AS showed excellent antimicrobial activitiesafter 10 repeated launderings.
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