Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1, 4-dicarboxylato)cadmium]
- Authors
- Ko, N.; Kim, J.
- Issue Date
- 2013
- Citation
- Acta Crystallographica Section E: Structure Reports Online, v.69, no.11, pp.m577 - m578
- Journal Title
- Acta Crystallographica Section E: Structure Reports Online
- Volume
- 69
- Number
- 11
- Start Page
- m577
- End Page
- m578
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/12225
- DOI
- 10.1107/S1600536813026287
- ISSN
- 1600-5368
- Abstract
- In the title compound, [Cd(C8F4O4)(C 2H5OH)2]n, the CdII cation sits on an inversion centre and is coordinated by six O atoms from four tetrafluorobenzene-1,4-dicarboxylate anions and two ethanol molecules in a distorted octahedral geometry. The anionic ligand is also located on an inversion centre, and connects four CdII cations, generating a two-dimensional polymeric layer parallel to the ab plane. Within the layer, the ethanol molecule links F and O atoms of the nearest anionic ligands via O - H⋯O and O - H⋯F hydrogen bonds. The ethyl group of the ethanol molecule is disordered over two positions with an occupancy ratio of 0.567(10):0.433(10).
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