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Highly active Pt-Pd alloy catalyst for oxygen reduction reaction in buffer solution

Authors
Lee, Young-WooOh, Sang-EunPark, Kyung-Won
Issue Date
Dec-2011
Publisher
ELSEVIER SCIENCE INC
Keywords
Shape control; Platinum; Palladium; Oxygen reduction; Buffer solution
Citation
ELECTROCHEMISTRY COMMUNICATIONS, v.13, no.12, pp.1300 - 1303
Journal Title
ELECTROCHEMISTRY COMMUNICATIONS
Volume
13
Number
12
Start Page
1300
End Page
1303
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/13529
DOI
10.1016/j.elecom.2011.07.022
ISSN
1388-2481
Abstract
Structure-controlled metallic catalysts have been well known to exhibit an improved electrocatalytic activity due to modulated surface structures favourable for electrochemical reactions. We synthesize octahedral Pt-Pd nanoparticles reducing metal ions with glycerol as a reducing agent in an aqueous solution. The octahedral Pt-Pd nanoparticles exhibit dominant (111} facets with homogeneous alloy formation between Pt and Pd atom. For oxygen reduction reaction in buffer solution, the octahedral Pt-Pd alloy electrocatalyst shows highly electrocatalytic activity. (C) 2011 Elsevier B.V. All rights reserved.
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