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Crystal structural observation of C-4V-symmetric tetrathiahemicarceplexes and their equilibria

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dc.contributor.authorKim, In-Kyu-
dc.contributor.authorKim, Jaheon-
dc.contributor.authorPaek, Kyungsoo-
dc.date.available2018-05-10T08:31:42Z-
dc.date.created2018-04-17-
dc.date.issued2011-11-09-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/13539-
dc.description.abstractThe crystal structures of tetrathiahemicarceplexes 1,4-diiodobenzene@1 and 4-iodotoluene@1 are reported. From the crystal structures and H-1 NMR experiment the kinetic versus thermodynamic complexation shifts of 4-iodotoluene@1 were observed. The four thia groups of tetrathiahemicarceplex cooperatively built the bottleneck' leading to the equilibrium shift of carceroisomers. (C) 2011 Elsevier Ltd. All rights reserved.-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.relation.isPartOfTETRAHEDRON LETTERS-
dc.subjectASSEMBLING HETERODIMERIC CAPSULE-
dc.subjectORIENTATIONAL ISOMERISM-
dc.subjectHYDROGEN-BONDS-
dc.subjectANION-BINDING-
dc.subjectCARCEPLEXES-
dc.titleCrystal structural observation of C-4V-symmetric tetrathiahemicarceplexes and their equilibria-
dc.typeArticle-
dc.identifier.doi10.1016/j.tetlet.2011.09.007-
dc.type.rimsART-
dc.identifier.bibliographicCitationTETRAHEDRON LETTERS, v.52, no.45, pp.6011 - 6014-
dc.description.journalClass1-
dc.identifier.wosid000296548400027-
dc.identifier.scopusid2-s2.0-80053582581-
dc.citation.endPage6014-
dc.citation.number45-
dc.citation.startPage6011-
dc.citation.titleTETRAHEDRON LETTERS-
dc.citation.volume52-
dc.contributor.affiliatedAuthorKim, Jaheon-
dc.contributor.affiliatedAuthorPaek, Kyungsoo-
dc.type.docTypeArticle-
dc.subject.keywordAuthorCarceroisomer-
dc.subject.keywordAuthorOrientational isomer-
dc.subject.keywordAuthorTetrathiahemicarceplex-
dc.subject.keywordAuthorBottleneck effect-
dc.subject.keywordPlusASSEMBLING HETERODIMERIC CAPSULE-
dc.subject.keywordPlusORIENTATIONAL ISOMERISM-
dc.subject.keywordPlusHYDROGEN-BONDS-
dc.subject.keywordPlusANION-BINDING-
dc.subject.keywordPlusCARCEPLEXES-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
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