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Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

Authors
Jeong, Kyung SeokLee, Bo HyungLi, QiaoweiChoi, Sang BeomKim, JaheonJeong, Nakcheol
Issue Date
2011
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.13, no.5, pp.1277 - 1279
Journal Title
CRYSTENGCOMM
Volume
13
Number
5
Start Page
1277
End Page
1279
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/14600
DOI
10.1039/c0ce00426j
ISSN
1466-8033
Abstract
A near identical MOF from the reaction between a homochiral ligand and La-III ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.
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