Molecular recognition of a fluoride anion receptor: the importance of C-H (N-H)center dot center dot center dot F- and "electropositive field space"center dot center dot center dot F- interactions
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yan, Shihai | - |
dc.contributor.author | Cho, Seung Joo | - |
dc.contributor.author | Lee, Sang Joo | - |
dc.contributor.author | Kang, Sunwoo | - |
dc.contributor.author | Paek, Kyungsoo | - |
dc.contributor.author | Lee, Jin Yong | - |
dc.date.available | 2018-05-10T16:32:52Z | - |
dc.date.created | 2018-04-17 | - |
dc.date.issued | 2008 | - |
dc.identifier.issn | 1463-9076 | - |
dc.identifier.uri | http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/17708 | - |
dc.description.abstract | Host molecules effectively prefer to recognize F- ion rather than H2O through the upper rim, utilizing strong C-H (N-H)center dot center dot center dot F- interactions. The electropositive field space ("electropositive field space'') at the lower rim of the host molecules can also act as a good binding site for small anions such as F-. The electron withdrawing substituent at the para-position (X) makes the C(N)-H-a center dot center dot center dot F- and C(N)-H-a center dot center dot center dot O interactions much enhanced. The calculated vibrational frequencies and NMR chemical shifts are consistent with experimental trends. | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | - |
dc.subject | NEUTRON-DIFFRACTION DATA | - |
dc.subject | HOST-GUEST INTERACTIONS | - |
dc.subject | HYDROGEN-BONDS | - |
dc.subject | SELECTIVE FLUORESCENT | - |
dc.subject | IMIDAZOLIUM RECEPTOR | - |
dc.subject | BINDING-PROPERTIES | - |
dc.subject | ETHYLENE-GLYCOL | - |
dc.subject | SOLID-STATE | - |
dc.subject | PURE-SILICA | - |
dc.subject | AB-INITIO | - |
dc.title | Molecular recognition of a fluoride anion receptor: the importance of C-H (N-H)center dot center dot center dot F- and "electropositive field space"center dot center dot center dot F- interactions | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/b805821k | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.10, no.47, pp.7079 - 7084 | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000261741900003 | - |
dc.identifier.scopusid | 2-s2.0-57049169364 | - |
dc.citation.endPage | 7084 | - |
dc.citation.number | 47 | - |
dc.citation.startPage | 7079 | - |
dc.citation.title | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | - |
dc.citation.volume | 10 | - |
dc.contributor.affiliatedAuthor | Paek, Kyungsoo | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | NEUTRON-DIFFRACTION DATA | - |
dc.subject.keywordPlus | HOST-GUEST INTERACTIONS | - |
dc.subject.keywordPlus | HYDROGEN-BONDS | - |
dc.subject.keywordPlus | SELECTIVE FLUORESCENT | - |
dc.subject.keywordPlus | IMIDAZOLIUM RECEPTOR | - |
dc.subject.keywordPlus | BINDING-PROPERTIES | - |
dc.subject.keywordPlus | ETHYLENE-GLYCOL | - |
dc.subject.keywordPlus | SOLID-STATE | - |
dc.subject.keywordPlus | PURE-SILICA | - |
dc.subject.keywordPlus | AB-INITIO | - |
dc.description.journalRegisteredClass | scopus | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
Soongsil University Library 369 Sangdo-Ro, Dongjak-Gu, Seoul, Korea (06978)02-820-0733
COPYRIGHT ⓒ SOONGSIL UNIVERSITY, ALL RIGHTS RESERVED.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.