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Zinc(II) and copper(I)-ferrocenedicarboxylate polyhedron and polygon
- Authors
- Kim, Young S.; Kim, Jaheon; Kim, Don; Chae, Hee K.
- Issue Date
- 5-Jan-2007
- Publisher
- CHEMICAL SOC JAPAN
- Citation
- CHEMISTRY LETTERS, v.36, no.1, pp.150 - 151
- Journal Title
- CHEMISTRY LETTERS
- Volume
- 36
- Number
- 1
- Start Page
- 150
- End Page
- 151
- ISSN
- 0366-7022
- Abstract
- Metal organometallic carboxylates with unusual polyhedral and rectangular shapes have been prepared by the reaction of 1,1'-ferrocenedicarboxylic acid (H(2)FDCA) with Zn-II and Cu-II to give [Zn6O2(FDCA)(5)(H2O)(DMF)]center dot(DMF)(4) (1), [Zn8O4(FDCA)(6)(H2O)(3)]center dot(DMA)(4)center dot(H2O)(2) (2), and [CU4(FDCA)(2)] (3), respectively (DMF = N,N'-dimethylformamide; DMA = N,N'-dimethylacetoamide). SQUID data of zinc compounds show that iron ions of the ferrocene moieties in the compounds exhibit antiferromagnetic coupling.
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Related Researcher
- Kim, Ja heon
- College of Natural Sciences (Department of Chemistry)