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Supramolecular self-assembly of tin(IV) porphyrin channels stabilizing single-file chains of water molecules

Authors
Kim, HJJo, HJKim, JKim, SYKim, DKim, K
Issue Date
22-Jun-2005
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.7, pp.417 - 420
Journal Title
CRYSTENGCOMM
Volume
7
Start Page
417
End Page
420
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/19360
DOI
10.1039/b504841a
ISSN
1466-8033
Abstract
The supramolecular assembly of tin( IV) porphyrin equipped with six pyridyl groups, trans-diisonicotinate[meso-tetrakis(4-pyridyl) porphyrinato] tin( IV), generates a uniform channel lined with the pyridyl groups, in which the lattice water molecules are ordered into a single-file chain by hydrogen bonding between neighboring water molecules along the chain as well as hydrogen bonding between water molecules and the pyridyl lining of the channel.
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