Oligobisvelcraplex: Self-assembled linear oligomer by solvophobic pi-pi stacking interaction of bisvelcrands based on resorcin[4]arene
- Authors
- Ihm, H; Ahn, JS; Lah, MS; Ko, YH; Paek, K
- Issue Date
- 28-Oct-2004
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.6, no.22, pp.3893 - 3896
- Journal Title
- ORGANIC LETTERS
- Volume
- 6
- Number
- 22
- Start Page
- 3893
- End Page
- 3896
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/19956
- DOI
- 10.1021/ol048539f
- ISSN
- 1523-7060
- Abstract
- [GRAPHICS] Bisvelcrand 3 based on resorcin[4]arene was obtained by a stepwise route, and the formation of oligobisvelcraplex 3(n) by solvophobic pi-pi stacking interaction was observed. H-1 NMR spectroscopic studies revealed that DeltaG(pseudorotation)(double dagger) of oligobisvelcraplex 3(n) is 16.7 kcal mol(-1) in C6D5NO2 solution. The pulsed field gradient spin-echo (PGSE) NMR experiment and VPO experiment showed that the number of aggregation (n) ranges from 7 to 10 in CHCl3 solution at 298 K. In high concentration, bisvelcrand 3 tends to form gels or fiber.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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