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Thermal behavior of metallodendrimers possessing bis(terpyridinyl)Ru-(II) connectivity and different surface functionality
- Authors
- Hwang, SH; Yoo, KS; Moorefield, CN; Lee, SW; Newkome, GR
- Issue Date
- 15-Apr-2004
- Publisher
- WILEY-BLACKWELL
- Keywords
- metallodendrimers; Ru-(II) complexes; bis(terpyridinyl) complexes; glass transition; thermal stability; thermal properties; dendrimers
- Citation
- JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, v.42, no.8, pp.1487 - 1495
- Journal Title
- JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
- Volume
- 42
- Number
- 8
- Start Page
- 1487
- End Page
- 1495
- ISSN
- 0887-6266
- Abstract
- A series of metallodendrimers, assembled by means of bis(terpyridinyl)-Ru-(II) connectivity on poly(propylene imine) dendrimer scaffolds, with homogeneous or heterogeneous surfaces, were prepared. Differential scanning calorimetry and thermogravimetric analysis were used to determine their thermal behavior, glass-transition temperatures, and the decomposition kinetics and temperatures; no synergy effects for these properties were observed for the heterogeneously surfaced constructs in contrast to the corresponding homogeneously coated materials, which exhibited different values depending on their surface functionalities. (C) 2004 Wiley Periodicals, Inc.
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Related Researcher
- LEE, SANG WON
- College of Engineering (Department of Chemical)