Synthesis of Helical Polyisocyanide with Alkyne End-Group Using Grignard Reaction
DC Field | Value | Language |
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dc.contributor.author | Cho, M.-S. | - |
dc.contributor.author | Yu, J.-S. | - |
dc.contributor.author | Cho, J.-H. | - |
dc.contributor.author | Han, J.-W. | - |
dc.contributor.author | Kwark, Y.-J. | - |
dc.date.available | 2019-03-13T01:10:39Z | - |
dc.date.created | 2018-11-06 | - |
dc.date.issued | 2019-02 | - |
dc.identifier.issn | 1598-5032 | - |
dc.identifier.uri | http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/30686 | - |
dc.description.abstract | we could synthesize PI with alkyne terminal group by applying Grignard reaction. The Ni-Br bond at the polymer chain ends reacted with alkyne containing Grignard reagent, and the following reductive elimination rendered the PI with alkyne terminal group. However, the generated PI-alkyne adducts underwent dimerization process catalyzed by the resulting Ni(0) complexes. The phenomenon could be prevented by adding additional PMe3 ligands during the Grignard reaction, and resulting polymer showed well-defined MW, narrow MW distribution, and terminal alkyne groups. The current system provided simple route to form end-functionalized helical polymers using well-known chemistry. The resulting polymers might find its uses in preparing helical-coil block copolymer with coil polymers via Click chemistry. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | Polymer Society of Korea | - |
dc.relation.isPartOf | Macromolecular Research | - |
dc.title | Synthesis of Helical Polyisocyanide with Alkyne End-Group Using Grignard Reaction | - |
dc.type | Article | - |
dc.identifier.doi | 10.1007/s13233-019-7024-5 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Macromolecular Research, v.27, no.2, pp.212 - 214 | - |
dc.identifier.kciid | ART002438079 | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000460766600013 | - |
dc.identifier.scopusid | 2-s2.0-85055705752 | - |
dc.citation.endPage | 214 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 212 | - |
dc.citation.title | Macromolecular Research | - |
dc.citation.volume | 27 | - |
dc.contributor.affiliatedAuthor | Kwark, Y.-J. | - |
dc.identifier.url | https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART002438079 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.subject.keywordPlus | GROUP FUNCTIONALIZATION | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | NICKEL(II) | - |
dc.subject.keywordPlus | KINETICS | - |
dc.relation.journalResearchArea | Polymer Science | - |
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