Facile fabrication of porous Sn-based catalysts for electrochemical CO2 reduction to HCOOH and syngas
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, H. | - |
dc.contributor.author | Lee, H. | - |
dc.contributor.author | Lim, T. | - |
dc.contributor.author | Ahn, S.H. | - |
dc.date.available | 2019-03-13T01:32:29Z | - |
dc.date.created | 2018-09-12 | - |
dc.date.issued | 2018-10 | - |
dc.identifier.issn | 1226-086X | - |
dc.identifier.uri | http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/31172 | - |
dc.description.abstract | Porous Sn and Sn-based binary catalysts are facilely fabricated by an electrodeposition method. Varying conditions for Sn electrodeposition enables a control of Sn roughness, which exhibits a significant effect on catalytic performance for electrochemical CO2 reduction. At a specific applied potential, the porous Sn catalyst with relative roughness factor of 56.5 demonstrates a HCOOH Faradaic efficiency of 40.7% with a H2/CO ratio of 2.2. Further improvement of the HCOOH Faradaic efficiency to 59.2% is achieved by using a porous Sn0.29In0.71 catalyst. This catalyst also achieves a H2/CO ratio of 2.2, which can be used as syngas to produce value-added hydrocarbons. © 2018 The Korean Society of Industrial and Engineering Chemistry | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | Korean Society of Industrial Engineering Chemistry | - |
dc.relation.isPartOf | Journal of Industrial and Engineering Chemistry | - |
dc.subject | Binary alloys | - |
dc.subject | Carbon dioxide | - |
dc.subject | Catalysts | - |
dc.subject | Efficiency | - |
dc.subject | Electrodeposition | - |
dc.subject | Electrodes | - |
dc.subject | Fabrication | - |
dc.subject | Formic acid | - |
dc.subject | Indium alloys | - |
dc.subject | Synthesis gas | - |
dc.subject | Tin | - |
dc.subject | Applied potentials | - |
dc.subject | Catalytic performance | - |
dc.subject | CO2 reduction | - |
dc.subject | Electrodeposition methods | - |
dc.subject | Faradaic efficiencies | - |
dc.subject | Foam structure | - |
dc.subject | HCOOH | - |
dc.subject | Syn-gas | - |
dc.subject | Reduction | - |
dc.title | Facile fabrication of porous Sn-based catalysts for electrochemical CO2 reduction to HCOOH and syngas | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jiec.2018.05.036 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Journal of Industrial and Engineering Chemistry | - |
dc.identifier.kciid | ART002396925 | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000446144400024 | - |
dc.identifier.scopusid | 2-s2.0-85048739753 | - |
dc.citation.title | Journal of Industrial and Engineering Chemistry | - |
dc.contributor.affiliatedAuthor | Lim, T. | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.subject.keywordAuthor | Electrochemical CO2 reduction | - |
dc.subject.keywordAuthor | Foam structure | - |
dc.subject.keywordAuthor | Electrodeposition | - |
dc.subject.keywordAuthor | HCOOH | - |
dc.subject.keywordAuthor | Syngas | - |
dc.subject.keywordPlus | ACID FUEL-CELLS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | FORMIC-ACID | - |
dc.subject.keywordPlus | HYDROGEN EVOLUTION | - |
dc.subject.keywordPlus | METAL-ELECTRODES | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | SURFACES | - |
dc.subject.keywordPlus | FOAM | - |
dc.subject.keywordPlus | ELECTROCATALYSTS | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.description.journalRegisteredClass | scie | - |
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