Hydrogen generation from catalytic hydrolysis of sodium borohydride by a Cu and Mo promoted Co catalyst
- Authors
- Deonikar V.G.; Rathod P.V.; Pornea A.M.; Puguan J.M.C.; Park K.; Kim H.
- Issue Date
- Jun-2020
- Publisher
- Korean Society of Industrial Engineering Chemistry
- Keywords
- Hierarchical composites; Hydrogen production; Marigold-like microsphere; Sodium borohydride; Synergistic effect
- Citation
- Journal of Industrial and Engineering Chemistry, v.86, pp.167 - 177
- Journal Title
- Journal of Industrial and Engineering Chemistry
- Volume
- 86
- Start Page
- 167
- End Page
- 177
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/38705
- DOI
- 10.1016/j.jiec.2020.02.024
- ISSN
- 1226-086X
- Abstract
- Catalytic hydrolysis of chemical hydrides with the use of NaBH4 is a safe and effective way to provide hydrogen fuel for new energy vehicles and portable electronic devices. Herein we developed a Cu and Mo promoted Co hierarchical composites (Co1−xCuxMoO4) for hydrolysis of NaBH4 via an easy synthesis route. FESEM analysis depicts that the morphology of Co1−xCuxMoO4 hierarchical composites varied significantly from irregular microsphere to marigold microsphere to rose like morphology with the increase in Cu (x) ratio with respect to Co (1 − x). Flower-like morphological architecture and crystal configuration empower the supported catalyst to exhibit a remarkable catalytic activity and outstanding catalytic activity was obtained for marigold-like Co0.9Cu0.1MoO4 catalyst with an H2 generation rate of 1005.7 mL min−1 g−1, which confirms existence of synergistic effect between Co, Cu and Mo. Lower loading of Cu in Co1−xCuxMoO4 supported the active sites of Co to increase its catalytic activity. Additionally, the catalyst exhibits good recyclability after five successive runs of hydrolytic reaction, making it a robust catalyst for hydrolysis of NaBH4 and could be considered as a potential catalyst for portable hydrogen fuel systems. © 2020 The Korean Society of Industrial and Engineering Chemistry
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