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3-Dimensional Scanning of Entire Unit Cells in Single Nanoparticles.

Authors
Heo, JunyoungKang, DohunKim, SunginChun, HojeHan, ByungchanKim, Byung HyoPark, Jungwon
Issue Date
May-2022
Publisher
WILEY-V C H VERLAG GMBH
Keywords
Symmetry analysis; Atomic structures; Nanoparticles; Unit-cell analysis; Structure-activity relationships
Citation
CHEMNANOMAT, v.8, no.5
Journal Title
CHEMNANOMAT
Volume
8
Number
5
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/42351
DOI
10.1002/cnma.202200057
ISSN
2199-692X
Abstract
Properties of nanomaterials such as optical, electrical, and chemical properties are strongly correlated with lattice symmetry, making characterization of lattice symmetry essential. We introduce a symmetry analysis method using 3D atomic coordinates obtained by Brownian one-particle 3D reconstruction. The method allows direct and quantitative analysis of symmetrical properties and delivers local structural characteristics of individual platinum (Pt) nanoparticles in unit-cell level. Local structural deformations of the Pt nanoparticles such as lattice distortion and internal symmetry breakage are demonstrated, revealing that the crystal structure of sub-3 nm Pt nanoparticles generally maintains FCC crystallinity and exhibits localized deviation from their bulk counterpart.
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College of Engineering (Department of Materials Science and Engineering)
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