Equilibria of semi-volatile isothiazolinones between air and glass surfaces measured by gas chromatography and Raman spectroscopy
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sohn, Seungwoon | - |
dc.contributor.author | Huong, Vu Thi | - |
dc.contributor.author | Nguyen, Phuong-Dong | - |
dc.contributor.author | Ly, Nguyen Hoang | - |
dc.contributor.author | Jang, Soonmin | - |
dc.contributor.author | Lee, Hyewon | - |
dc.contributor.author | Lee, Cheolmin | - |
dc.contributor.author | Il Lee, Jung | - |
dc.contributor.author | Vasseghian, Yasser | - |
dc.contributor.author | Joo, Sang-Woo | - |
dc.contributor.author | Zoh, Kyung-Duk | - |
dc.date.accessioned | 2023-03-10T05:40:03Z | - |
dc.date.available | 2023-03-10T05:40:03Z | - |
dc.date.created | 2023-02-27 | - |
dc.date.issued | 2023-02 | - |
dc.identifier.issn | 0013-9351 | - |
dc.identifier.uri | http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/43365 | - |
dc.description.abstract | Trace amounts of semi-volatile organic compounds (SVOCs) of the two isothiazolinones of 2-methylisothiazol-3 (2H)-one (MIT) and 2-octyl-4-isothiazolin-3-one (OIT) were detected both in the air and on glass surfaces. Equilibria of SVOCs between air and glass were examined by solid phase microextraction-gas chromatography/mass spectrometry (SPME-GC/MS). Surface to air distribution ratios of Ksa for MIT and OIT were determined to be 5.10 m and 281.74 m, respectively, suggesting more abundant MIT in the gas phase by a factor of similar to 55. In addition, a facile method of silver nanocube (AgNC)-assisted surface-enhanced Raman scattering (SERS) has been developed for the rapid and sensitive detection of MIT and OIT on glass surfaces. According to MIT and OIT concentration-correlated SERS intensities of Raman peaks at similar to 1585 cm(-1) and similar to 1125 cm(-1), respectively. Their calibration curves have been obtained in the concentration ranges between 10(-3) to 10(-10) M and 10(-3) to 10(-11) M with their linearity of 0.9986 and 0.9989 for MIT and OIT, respectively. The limits of detection (LODs) of the two isothiazolinones were estimated at 10(-10) M, and 10(-11) M for MIT and OIT, respectively. Our results indicate that AgNC-assisted SERS spectra are a rapid and high-ultrasensitive method for the quantification of MIT and OIT in practical applications. The development of analytical methods and determination of the Ksa value obtained in this study can be applied to the prediction of the exposure to MIT and OIT from various chemical products and dynamic behaviors to assess human health risks in indoor environments. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | - |
dc.relation.isPartOf | ENVIRONMENTAL RESEARCH | - |
dc.title | Equilibria of semi-volatile isothiazolinones between air and glass surfaces measured by gas chromatography and Raman spectroscopy | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.envres.2022.114908 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ENVIRONMENTAL RESEARCH, v.218 | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000906374900004 | - |
dc.identifier.scopusid | 2-s2.0-85144032614 | - |
dc.citation.title | ENVIRONMENTAL RESEARCH | - |
dc.citation.volume | 218 | - |
dc.contributor.affiliatedAuthor | Joo, Sang-Woo | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0013935122022356?via%3Dihub | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.subject.keywordAuthor | Silver nanocubes | - |
dc.subject.keywordAuthor | Isothiazolinone | - |
dc.subject.keywordAuthor | Surface-enhanced Raman scattering | - |
dc.subject.keywordAuthor | Surface-air equilibria | - |
dc.subject.keywordPlus | SILVER NANOCUBES | - |
dc.subject.keywordPlus | RISK-ASSESSMENT | - |
dc.subject.keywordPlus | SERS | - |
dc.subject.keywordPlus | METHYLISOTHIAZOLINONE | - |
dc.subject.keywordPlus | PRODUCTS | - |
dc.subject.keywordPlus | VAPOR | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | MASS | - |
dc.relation.journalResearchArea | Environmental Sciences & Ecology | - |
dc.relation.journalResearchArea | Public, Environmental & Occupational Health | - |
dc.relation.journalWebOfScienceCategory | Environmental Sciences | - |
dc.relation.journalWebOfScienceCategory | Public, Environmental & Occupational Health | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
Soongsil University Library 369 Sangdo-Ro, Dongjak-Gu, Seoul, Korea (06978)02-820-0733
COPYRIGHT ⓒ SOONGSIL UNIVERSITY, ALL RIGHTS RESERVED.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.