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Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(ii) centres and 2-nitroimidazolates
- Authors
- Jung, Cheolwon; Choi, Sang Beom; Park, Jaewoo; Jung, Minji; Kim, Jonghoon; Oh, Hyunchul; Kim, Jaheon
- Issue Date
- Mar-2023
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, v.59, no.27, pp.4040 - 4043
- Journal Title
- CHEMICAL COMMUNICATIONS
- Volume
- 59
- Number
- 27
- Start Page
- 4040
- End Page
- 4043
- ISSN
- 1359-7345
- Abstract
- Cu(ii)-based zeolitic imidazolates (Cu-ZIFs), Cu-ZIF-gis and -rho, formulated as Cu(nIm)(2) (nIm = 2-nitroimidazolate) have highly-flattened tetrahedral coordination geometry. Cu-ZIF-gis has 2.4 & ANGS; cylindrical pores that can adsorb H-2 gas, and Cu-ZIF-rho has 19.8 & ANGS; cages with a BET surface area of 1320 m(2) g(-1).
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Related Researcher
- Kim, Ja heon
- College of Natural Sciences (Department of Chemistry)