Luminescence and local structure of Mn-doped ZnS hybrid crystal with two-dimensional platelet morphology
- Authors
- 이동렬; 장점석; 김은선; 이재성; 신남수; 최선희
- Issue Date
- 2009
- Publisher
- ELSEVIER SCIENCE BV
- Citation
- CHEMICAL PHYSICS LETTERS, v.468, no.4-6, pp.253 - 256
- Journal Title
- CHEMICAL PHYSICS LETTERS
- Volume
- 468
- Number
- 4-6
- Start Page
- 253
- End Page
- 256
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/5965
- DOI
- 10.1016/j.cplett.2008.12.045
- ISSN
- 0009-2614
- Abstract
- Mn-doped ZnS hybrid crystals with two-dimensional platelet morphology were prepared and their luminescence properties were studied with the variation of Mn concentration. The photoluminescence derived from Mn(2+) increased with increasing Mn concentration to x = 0.2 in Zn(1) (x)Mn(x)S(en)(0.5) (en = ethylenediamine), but further increase reduced the photoluminescence. According to structural study by synchrotron X-ray techniques, the bond distances of Mn-N and Mn-S were longer than those of Zn-N and Zn-S in ZnS(en)(0.5), respectively. Manganese atoms were most highly doped into tetrahedral Zn sites without impurities at x = 0.2, where the maximum photoluminescence was observed. (C) 2008 Elsevier B.V. All rights reserved.
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Collections - College of Natural Sciences > Department of Physics > 1. Journal Articles
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