Siloxane-Terminated Solubilizing Side Chains: Bringing Conjugated Polymer Backbones Closer and Boosting Hole Mobilities in Thin-Film Transistors
DC Field | Value | Language |
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dc.contributor.author | Mei, Jianguo | - |
dc.contributor.author | Kim, Do Hwan | - |
dc.contributor.author | Ayzner, Alexander L. | - |
dc.contributor.author | Toney, Michael F. | - |
dc.contributor.author | Bao, Zhenan | - |
dc.date.available | 2018-05-08T04:44:58Z | - |
dc.date.created | 2018-04-18 | - |
dc.date.issued | 2011-12 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/6003 | - |
dc.description.abstract | We introduce a novel siloxane-terminated solubilizing group and demonstrate its effectiveness as a side chain in an isoindigo-based conjugated polymer. An average hole mobility of 2.00 cm(2) V-1 s(-1) (with a maximum mobility of 2.48 cm(2) V-1 s(-1)), was obtained from solution-processed thin-film transistors, one of the highest mobilities reported to date. In contrast, the reference polymer with a branched alkyl side chain gave an average hole mobility of 0.30 cm(2) V-1 s(-1) and a maximum mobility of 0.57 cm(2) V-1 s(-1). This is largely explained by the polymer packing: our new polymer exhibited a pi-pi stacking distance of 3.58 angstrom, while the reference polymer showed a distance of 3.76 angstrom. | - |
dc.language | 영어 | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.title | Siloxane-Terminated Solubilizing Side Chains: Bringing Conjugated Polymer Backbones Closer and Boosting Hole Mobilities in Thin-Film Transistors | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ja209328m | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.50, pp.20130 - 20133 | - |
dc.description.journalClass | 1 | - |
dc.identifier.wosid | 000298713600028 | - |
dc.identifier.scopusid | 2-s2.0-83755168258 | - |
dc.citation.endPage | 20133 | - |
dc.citation.number | 50 | - |
dc.citation.startPage | 20130 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 133 | - |
dc.contributor.affiliatedAuthor | Kim, Do Hwan | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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