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Reduced Viscosity of the Free Surface in Entangled Polymer Melt Films

Authors
이동렬C. LIJ. KOOL.B.LURIOM. RAFAILOVICHM.K.ENDOHS. NARAYANANS.K.SINHATADANORI KOGAC. LIJ. KOOL.B.LURIOM. RAFAILOVICHM.K.ENDOHS. NARAYANANS.K.SINHATADANORI KOGA
Issue Date
2010
Publisher
AMER PHYSICAL SOC
Citation
PHYSICAL REVIEW LETTERS, v.104, no.6
Journal Title
PHYSICAL REVIEW LETTERS
Volume
104
Number
6
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/6016
DOI
10.1103/PhysRevLett.104.066101
ISSN
0031-9007
Abstract
By embedding "dilute'' gold nanoparticles in single polystyrene thin films as "markers'', we probe the local viscosity of the free surface at temperatures far above the glass transition temperature (T(g)). The technique used was x-ray photon correlation spectroscopy with resonance-enhanced x-ray scattering. The results clearly showed the surface viscosity is about 30% lower than the rest of the film. We found that this reduction is strongly associated with chain entanglements at the free surface rather than the reduction in T(g).
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