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Electrocatalytic Oxidation Reactions of Pt Hexapod Nanoparticles

Authors
Kwak, Da-HeeLee, Young-WooHan, Sang-BeomLee, Jin-YeonZhoh, Choon-KooPark, Kyung-Won
Issue Date
10-Sep-2015
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Pt; Hexapod; Nanoparticles; Electro-oxidation reactions
Citation
ELECTROCHIMICA ACTA, v.176, pp.790 - 796
Journal Title
ELECTROCHIMICA ACTA
Volume
176
Start Page
790
End Page
796
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/8647
DOI
10.1016/j.electacta.2015.07.075
ISSN
0013-4686
Abstract
The Pt nanoparticles were synthesized using a polyol process in the presence of additives such as FeCl3, NaNO3, and PVP. In particular, the Pt nanoparticles with a hexapod structure (Pt-FNP) were formed without agglomeration in the presence of additive ions of Fe3+ and NO3- with PVP. The Pt-FNP exhibited an improved electrocatalytic activity for electro-oxidation reactions of methanol, ethanol, and formic acid due to dominant {111} facets formed as a result of a slow growth rate during the chemical process. (C) 2015 Elsevier Ltd. All rights reserved.
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