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Enhancement of Electrical Conductivity of Carbon Nanotube Fibers by Copper Sulfide Plating

Authors
Kim, SoyoungKim, SunhwaKim, Young HoKu, Bon-CheolJeong, Youngjin
Issue Date
30-Apr-2015
Publisher
KOREAN FIBER SOC
Keywords
Carbon nanotube fiber; Electrical conductivity; Copper sulfide; Direct spinning; Mechanical property
Citation
FIBERS AND POLYMERS, v.16, no.4, pp.769 - 773
Journal Title
FIBERS AND POLYMERS
Volume
16
Number
4
Start Page
769
End Page
773
URI
http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/8750
DOI
10.1007/s12221-015-0769-3
ISSN
1229-9197
Abstract
The present study aimed to enhance the electrical conductivity of carbon nanotube (CNT) fibers by introducing copper sulfide (CuS) into them. CuS forms a very stable compound with an electrical conductivity as high as 106 S/m, and it was introduced into CNT fibers by treating them with polyethyleneimine (PEI) to introduce amine groups on the CNTs. The CNT fibers were then treated with a solution of copper sulfate/sodium thiosulfate, which increased their electrical conductivity by >= 100 % (4x10(5) S/m) relative to that of untreated CNT fibers. This study also examined how the CuS plating changed the structure, morphology, and mechanical properties of CNT fibers. The results indicate that the modulus of elasticity of CuS-plated CNTs increased by 2.86 times (11.34 N/tex) and the elongation-at-break decreased by half.
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