Tailoring the water adsorption properties of MIL-101 metal-organic frameworks by partial functionalization
- Authors
- Ko, Nakeun; Choi, Pan Gyu; Hong, Jisu; Yeo, Miso; Sung, Siyoung; Cordova, Kyle E.; Park, Hye Jeong; Yang, Jin Kuk; Kim, Jaheon
- Issue Date
- 2015
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- JOURNAL OF MATERIALS CHEMISTRY A, v.3, no.5, pp.2057 - 2064
- Journal Title
- JOURNAL OF MATERIALS CHEMISTRY A
- Volume
- 3
- Number
- 5
- Start Page
- 2057
- End Page
- 2064
- URI
- http://scholarworks.bwise.kr/ssu/handle/2018.sw.ssu/9807
- DOI
- 10.1039/c4ta04907a
- ISSN
- 2050-7488
- Abstract
- MIL-101 and MIL-101-NH2 were partially modified to incorporate various functional groups that are capable of forming hydrogen bonds with water. Specifically, MIL-101-NH2 was partially functionalized with -NHCONHCH2CH3 (-UR2), -NHCOCHCHCOOH (-Mal), or -NH(CH2)(3)SO3H (-3SO(3)H) and MIL-101 was partially functionalized with -COOH in order to investigate the effect of these groups on the water sorption properties when compared to the pristine versions. The MIL-101 derivatives were synthesized by either post-synthetic modification of MIL-101-NH2 or through direct synthesis using a mixed linker strategy. The ratios of the incorporated functional groups were determined by H-1-NMR analyses and the porosity changes were revealed by N-2 gas adsorption measurements at 77 K. Water sorption isotherms at 298 K conclude that the incorporation of -3SO(3)H enhances the water vapour uptake capacity at a low relative pressure (P/P-0 = 0.30), whereas -UR2 and -Mal retard water adsorption in MIL-101-NH2. The partial incorporation of -COOH in MIL-101 exhibits a steeper water uptake at lower pressure (P/P-0 = 0.40) than MIL-101-NH2. Interestingly, a greater -COOH content within the MIL-101 framework reduces the water uptake capacity. These results indicate that even partial functionalization of MIL-101 induces noticeably large changes in the water adsorption properties.
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