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Pb-3[C-6(CH3)(3)(CO2)(3)H-6](2)[DMF](3): first layered Pb-Kemp's triacid complex
- Issue Date
- Aug-2015
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, v.51, no.67, pp 13166 - 13169
- Pages
- 4
- Journal Title
- CHEMICAL COMMUNICATIONS
- Volume
- 51
- Number
- 67
- Start Page
- 13166
- End Page
- 13169
- ISSN
- 1359-7345
1364-548X
- Abstract
- An unprecedented layered Pb-Kemp's triacid compound, Pb-3[C-6(CH3)(3)(CO2)(3)H-6](2)[DMF](3), has been synthesized. The material exhibits a selective CO2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under solvothermal conditions using Pb2+ and Cd2+ with Kemp's triacid reveals higher selectivity of Cd2+ over Pb2+.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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