A molecular porous zirconium-organic material exhibiting highly selective CO2 adsorption, high thermal stability, reversible hydration, facile ligand exchange and exclusive dimerization of phenylacetylene
DC Field | Value | Language |
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dc.contributor.author | Lee, Nam Hee | - |
dc.contributor.author | Lee, Dong Woo | - |
dc.contributor.author | Yeo, Hakmin | - |
dc.contributor.author | Kwak, Kyungwon | - |
dc.contributor.author | Chun, Hyang Sook | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-03-09T00:42:34Z | - |
dc.date.issued | 2014-07-07 | - |
dc.identifier.issn | 1466-8033 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/13951 | - |
dc.description.abstract | A new molecular porous zirconium-organic material, Zr{[NC5H3(CO2)(2)](2)(OH2)(2)}center dot 1.3H(2)O (CAUMOF-12) has been synthesized by a hydrothermal reaction using Zr(NO3)(4), 2,6-NC5H3(CO2H)(2), HNO3 and water at 180 degrees C. Single-crystal X-ray diffraction was used to determine the crystal structure of the reported material. Although the material can be classified as a molecular compound, CAUMOF-12 exhibits a pseudo-three-dimensional open-framework structure with void spaces obtained by intermolecular hydrogen bonds. CAUMOF-12 reveals differential gas adsorption characteristics and high thermal stability. Reversible hydration, facile ligand exchange reactions, and exclusive dimerization of phenylacetylene for CAUMOF-12 are presented, as are electronic structure calculations. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A molecular porous zirconium-organic material exhibiting highly selective CO2 adsorption, high thermal stability, reversible hydration, facile ligand exchange and exclusive dimerization of phenylacetylene | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c4ce00253a | - |
dc.identifier.bibliographicCitation | CRYSTENGCOMM, v.16, no.25, pp 5619 - 5626 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000337126500017 | - |
dc.identifier.scopusid | 2-s2.0-84902097036 | - |
dc.citation.endPage | 5626 | - |
dc.citation.number | 25 | - |
dc.citation.startPage | 5619 | - |
dc.citation.title | CRYSTENGCOMM | - |
dc.citation.volume | 16 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | BOND-VALENCE PARAMETERS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE CAPTURE | - |
dc.subject.keywordPlus | EXCEPTIONAL STABILITY | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | FRAMEWORK UIO-66 | - |
dc.subject.keywordPlus | GAS-ADSORPTION | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | ACETYLENES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | HYDROGEN | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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