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Determination of Water Content in Bioethanol Using the 1 H NMR Chemical Shift Change

Authors
Yoon, JeongbinYun, SuyeonKim, ByungjooAhn, SangdooChoi, Kihwan
Issue Date
Apr-2019
Publisher
Wiley Blackwell
Keywords
1 H NMR; Bioethanol; Chemical shift; qNMR; Water content
Citation
Bulletin of the Korean Chemical Society, v.40, no.4, pp 313 - 316
Pages
4
Journal Title
Bulletin of the Korean Chemical Society
Volume
40
Number
4
Start Page
313
End Page
316
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/18582
DOI
10.1002/bkcs.11692
ISSN
0253-2964
1229-5949
Abstract
Chemical shift change in 1 H NMR spectroscopy was used to determine water content in bioethanol. As water content in ethanol is increased, the proton peaks shifted to down-field due to the change in the microstructure of the water-ethanol mixture. The linear correlation between water content and chemical shift change enables the evaluation of water content in bioethanol. Because the same relationship between chemical shift change and the water content is obtained for both ethanol and bioethanol, water content in bioethanol can be determined using the calibration curve obtained with anhydrous ethanol. The developed method was validated by comparison to the results of Karl Fischer titration and was applied to commercially available bioethanols. © 2019 Korean Chemical Society, Seoul & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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