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Selective Perborate Signaling by Deprotection of Fluorescein and Resorufin Acetates

Authors
Choi, Myung GilCha, SunyoungPark, Ji EunLee, HaekyungJeon, Hye LimChang, Suk-Kyu
Issue Date
Apr-2010
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.12, no.7, pp 1468 - 1471
Pages
4
Journal Title
ORGANIC LETTERS
Volume
12
Number
7
Start Page
1468
End Page
1471
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/22512
DOI
10.1021/ol100126c
ISSN
1523-7060
1523-7052
Abstract
The acetate derivatives of fluorescein and resorufin exhibited a prominent turn-on type signaling behavior toward BO3- Ions over other common anions. Signaling is based on the selective deprotection of acetate groups by perborate, which resulted in significant chromogenic and fluorogenic signaling. Compound 1 also exhibited a pronounced perborate selectivity over other commonly used oxidants in 90% aqueous acetonitrile solution.
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