Selective Perborate Signaling by Deprotection of Fluorescein and Resorufin Acetates
- Authors
- Choi, Myung Gil; Cha, Sunyoung; Park, Ji Eun; Lee, Haekyung; Jeon, Hye Lim; Chang, Suk-Kyu
- Issue Date
- Apr-2010
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.12, no.7, pp 1468 - 1471
- Pages
- 4
- Journal Title
- ORGANIC LETTERS
- Volume
- 12
- Number
- 7
- Start Page
- 1468
- End Page
- 1471
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/22512
- DOI
- 10.1021/ol100126c
- ISSN
- 1523-7060
1523-7052
- Abstract
- The acetate derivatives of fluorescein and resorufin exhibited a prominent turn-on type signaling behavior toward BO3- Ions over other common anions. Signaling is based on the selective deprotection of acetate groups by perborate, which resulted in significant chromogenic and fluorogenic signaling. Compound 1 also exhibited a pronounced perborate selectivity over other commonly used oxidants in 90% aqueous acetonitrile solution.
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- There are no files associated with this item.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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