Solid-Phase Synthesis of Unsymmetrical trans-Stilbenes
- Authors
- Cho, Chul-Hee; Kim, Chul-Bae; Park, Kwangyong
- Issue Date
- Jan-2010
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF COMBINATORIAL CHEMISTRY, v.12, no.1, pp 45 - 50
- Pages
- 6
- Journal Title
- JOURNAL OF COMBINATORIAL CHEMISTRY
- Volume
- 12
- Number
- 1
- Start Page
- 45
- End Page
- 50
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/22698
- DOI
- 10.1021/cc900099g
- ISSN
- 1520-4766
1520-4774
- Abstract
- A small library of fluorescent and unsymmetrical trans-stilbene compounds was efficiently produced by a solid-phase synthetic approach using the sulfonate-based traceless linker system. Nickel (0)-catalyzed cleavage/cross-coupling of polymer-bound stilbenesulfonates with aryl Grignard reagents generated the desired trans-stilbenes at high yield by the multifunctional release facilitating the additional diversification of the library. The luminescent properties of trans-stilbenes are assessed, and the influence of alkyl substituents on their photophysical properties is discussed.
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Collections - College of Engineering > School of Chemical Engineering and Material Science > 1. Journal Articles
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