Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5
DC Field | Value | Language |
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dc.contributor.author | Kim, Min Kyung | - |
dc.contributor.author | Jo, Vinna | - |
dc.contributor.author | Lee, Dong Woo | - |
dc.contributor.author | Ok, Kang Min | - |
dc.date.available | 2019-05-30T02:35:35Z | - |
dc.date.issued | 2010-07-14 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.issn | 1477-9234 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/22820 | - |
dc.description.abstract | A new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5 has been synthesized by a solid-state reaction under vacuum using Bi2O3, TeO2, and TeCl4 as reagents. The structure of Bi3Te4O10Cl5 has been determined by single-crystal X-ray diffraction. Bi3Te4O10Cl5 contains two different lone pair cations, Bi3+ and Te4+ that are in asymmetric coordination environments. Bi3Te4O10Cl5 has a novel two-dimensional layered structure consisting of distorted BiO4Cl2 octahedra, BiO4Cl3 polyhedra, TeO4 polyhedra, and isolated Cl-ions. Complete structural analysis, infrared spectrum, thermogravimetric analysis, and dipole moment calculations are presented. Crystal data: Bi3Te4O10Cl5, monoclinic, space group C2/m (No. 12), a = 15.372(3) angstrom, b = 4.1004(7) angstrom, c = 13.301(2) angstrom, beta = 98.336(5)degrees, V = 829.5(2) angstrom(3), and Z = 2. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5 | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/b927286k | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, v.39, no.26, pp 6037 - 6042 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000279098700014 | - |
dc.identifier.scopusid | 2-s2.0-77953853943 | - |
dc.citation.endPage | 6042 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 6037 | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.citation.volume | 39 | - |
dc.type.docType | Article | - |
dc.publisher.location | 영국 | - |
dc.subject.keywordPlus | BOND-VALENCE PARAMETERS | - |
dc.subject.keywordPlus | POWDER DIFFRACTION DATA | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | CENTER DISTORTION | - |
dc.subject.keywordPlus | LONE PAIRS | - |
dc.subject.keywordPlus | BR | - |
dc.subject.keywordPlus | STEREOCHEMISTRY | - |
dc.subject.keywordPlus | CL | - |
dc.subject.keywordPlus | OXYHALIDES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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