Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5
- Authors
- Kim, Min Kyung; Jo, Vinna; Lee, Dong Woo; Ok, Kang Min
- Issue Date
- 14-Jul-2010
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- DALTON TRANSACTIONS, v.39, no.26, pp 6037 - 6042
- Pages
- 6
- Journal Title
- DALTON TRANSACTIONS
- Volume
- 39
- Number
- 26
- Start Page
- 6037
- End Page
- 6042
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/22820
- DOI
- 10.1039/b927286k
- ISSN
- 1477-9226
1477-9234
- Abstract
- A new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5 has been synthesized by a solid-state reaction under vacuum using Bi2O3, TeO2, and TeCl4 as reagents. The structure of Bi3Te4O10Cl5 has been determined by single-crystal X-ray diffraction. Bi3Te4O10Cl5 contains two different lone pair cations, Bi3+ and Te4+ that are in asymmetric coordination environments. Bi3Te4O10Cl5 has a novel two-dimensional layered structure consisting of distorted BiO4Cl2 octahedra, BiO4Cl3 polyhedra, TeO4 polyhedra, and isolated Cl-ions. Complete structural analysis, infrared spectrum, thermogravimetric analysis, and dipole moment calculations are presented. Crystal data: Bi3Te4O10Cl5, monoclinic, space group C2/m (No. 12), a = 15.372(3) angstrom, b = 4.1004(7) angstrom, c = 13.301(2) angstrom, beta = 98.336(5)degrees, V = 829.5(2) angstrom(3), and Z = 2.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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