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TOF-2: A large 1D channel thorium organic framework
- Issue Date
- Mar-2008
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.12, pp 3762 - +
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume
- 130
- Number
- 12
- Start Page
- 3762
- End Page
- +
- ISSN
- 0002-7863
1520-5126
- Abstract
- A new neutral 1D channel thorium organic framework material (TOF-2) has been synthesized under hydrothermal conditions. TOF-2 exhibits a hexagonal channel structure consisting of eight-coordinate ThO6F2 polyhedra and 1,3,5-benzentricarboxylate ligands. The channels run along the c-axis and are approximately 13 angstrom in diameter. The single-crystal X-ray structure suggests that the amount of void space is 41%. The structure is stable to ca. 400 degrees C. Gas adsorption measurements show deferential gas uptake behavior.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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