Solid-phase synthesis of biphenyls and terphenyls by the traceless multifunctional cleavage of polymer-bound arenesulfonates
- Authors
- Cho, Chul-Hee; Park, Heon; Park, Min-Ah; Ryoo, Tae-Yong; Lee, Yoon-Sik; Park, Kwnagyong
- Issue Date
- Jul-2005
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- biaryls; cross-coupling; solid-phase synthesis; sulfonate; traceless multifunctional cleavage
- Citation
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2005, no.15, pp 3177 - 3181
- Pages
- 5
- Journal Title
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 2005
- Number
- 15
- Start Page
- 3177
- End Page
- 3181
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/24562
- DOI
- 10.1002/ejoc.200500279
- ISSN
- 1434-193X
1099-0690
- Abstract
- Nickel-catalyzed reactions between polymer-bound arene-sulfonates and aryl Grignard reagents produce unfunctionalized biphenyls and terphenyls in good yields through reductive cleavage/cross-coupling of the C-S bond. This novel traceless multifunctional cleavage strategy appears to be a powerful tool for the preparation of large oligophenyl libraries, because it allows the introduction of diversity concomitantly with the release of the target compounds. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
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Collections - College of Engineering > School of Chemical Engineering and Material Science > 1. Journal Articles
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