Visible Light-Induced Aromatic Difluoroalkylation
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, Jaehun | - |
dc.contributor.author | Kim, Eunjin | - |
dc.contributor.author | You, Youngmin | - |
dc.contributor.author | Cho, Eun Jin | - |
dc.date.available | 2019-07-16T04:57:24Z | - |
dc.date.issued | 2014-09 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.issn | 1615-4169 | - |
dc.identifier.uri | https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/28438 | - |
dc.description.abstract | Difluoroalkylated aromatics are important structural motifs in pharmaceutical and agrochemical applications. Herein, we report their synthesis by a mild, efficient, and convenient method using visible light photoredox catalysis. A variety of unactivated aromatics were difluoroalkylated with ethyl 2-bromo-2,2-difluoroacetate (BrCF2CO2Et) in the presence of the triscyclometalated Ir complex fac-[Ir(ppy)(3)] under visible light irradiation at room temperature. It is shown that reaction outcomes containing the CF2CO2Et moiety can be converted to a variety of other CF2-containing aromatics, demonstrating the synthetic utility of the present method. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Visible Light-Induced Aromatic Difluoroalkylation | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/adsc.201400542 | - |
dc.identifier.bibliographicCitation | ADVANCED SYNTHESIS & CATALYSIS, v.356, no.13, pp 2741 - 2748 | - |
dc.description.isOpenAccess | N | - |
dc.identifier.wosid | 000342905600002 | - |
dc.identifier.scopusid | 2-s2.0-85027931643 | - |
dc.citation.endPage | 2748 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 2741 | - |
dc.citation.title | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.volume | 356 | - |
dc.type.docType | Article | - |
dc.publisher.location | 독일 | - |
dc.subject.keywordAuthor | aromatics | - |
dc.subject.keywordAuthor | difluoroalkylation | - |
dc.subject.keywordAuthor | heteroaromatics | - |
dc.subject.keywordAuthor | iridium | - |
dc.subject.keywordAuthor | visible light | - |
dc.subject.keywordPlus | COPPER-MEDIATED DIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | C-H ACTIVATION | - |
dc.subject.keywordPlus | PHOTOREDOX CATALYSIS | - |
dc.subject.keywordPlus | TRIFLUOROMETHYLATION | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | ARYL | - |
dc.subject.keywordPlus | PERFLUOROALKYLATION | - |
dc.subject.keywordPlus | PHOSPHONATES | - |
dc.subject.keywordPlus | HETEROARENES | - |
dc.subject.keywordPlus | HETEROCYCLES | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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