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Cited 115 time in webofscience Cited 119 time in scopus
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Visible Light-Induced Aromatic Difluoroalkylation

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dc.contributor.authorJung, Jaehun-
dc.contributor.authorKim, Eunjin-
dc.contributor.authorYou, Youngmin-
dc.contributor.authorCho, Eun Jin-
dc.date.available2019-07-16T04:57:24Z-
dc.date.issued2014-09-
dc.identifier.issn1615-4150-
dc.identifier.issn1615-4169-
dc.identifier.urihttps://scholarworks.bwise.kr/cau/handle/2019.sw.cau/28438-
dc.description.abstractDifluoroalkylated aromatics are important structural motifs in pharmaceutical and agrochemical applications. Herein, we report their synthesis by a mild, efficient, and convenient method using visible light photoredox catalysis. A variety of unactivated aromatics were difluoroalkylated with ethyl 2-bromo-2,2-difluoroacetate (BrCF2CO2Et) in the presence of the triscyclometalated Ir complex fac-[Ir(ppy)(3)] under visible light irradiation at room temperature. It is shown that reaction outcomes containing the CF2CO2Et moiety can be converted to a variety of other CF2-containing aromatics, demonstrating the synthetic utility of the present method.-
dc.format.extent8-
dc.language영어-
dc.language.isoENG-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleVisible Light-Induced Aromatic Difluoroalkylation-
dc.typeArticle-
dc.identifier.doi10.1002/adsc.201400542-
dc.identifier.bibliographicCitationADVANCED SYNTHESIS & CATALYSIS, v.356, no.13, pp 2741 - 2748-
dc.description.isOpenAccessN-
dc.identifier.wosid000342905600002-
dc.identifier.scopusid2-s2.0-85027931643-
dc.citation.endPage2748-
dc.citation.number13-
dc.citation.startPage2741-
dc.citation.titleADVANCED SYNTHESIS & CATALYSIS-
dc.citation.volume356-
dc.type.docTypeArticle-
dc.publisher.location독일-
dc.subject.keywordAuthoraromatics-
dc.subject.keywordAuthordifluoroalkylation-
dc.subject.keywordAuthorheteroaromatics-
dc.subject.keywordAuthoriridium-
dc.subject.keywordAuthorvisible light-
dc.subject.keywordPlusCOPPER-MEDIATED DIFLUOROMETHYLATION-
dc.subject.keywordPlusC-H ACTIVATION-
dc.subject.keywordPlusPHOTOREDOX CATALYSIS-
dc.subject.keywordPlusTRIFLUOROMETHYLATION-
dc.subject.keywordPlusALKENES-
dc.subject.keywordPlusARYL-
dc.subject.keywordPlusPERFLUOROALKYLATION-
dc.subject.keywordPlusPHOSPHONATES-
dc.subject.keywordPlusHETEROARENES-
dc.subject.keywordPlusHETEROCYCLES-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Applied-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.description.journalRegisteredClasssci-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
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