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Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
- Authors
- Iqbal, Naeem; Choi, Sungkyu; Kim, Eunjin; Cho, Eun Jin
- Issue Date
- Dec-2012
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, v.77, no.24, pp 11383 - 11387
- Pages
- 5
- Journal Title
- JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 77
- Number
- 24
- Start Page
- 11383
- End Page
- 11387
- ISSN
- 0022-3263
1520-6904
- Abstract
- A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF3I, Ru(Phen)(3)Cl-2, and DBU. This process works especially well for terminal alkenes to give alkenyl-CF3 products with only E-stereochemistry. The mild reaction conditions enable the trifluoromethylation of a range of alkenes that bear various functional groups.
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