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Trifluoromethylation of heterocycles via visible light photoredox catalysis
- Authors
- Iqbal, Naeem; Choi, Sungkyu; Ko, Euna; Cho, Eun Jin
- Issue Date
- Apr-2012
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Visible light; Photoredox catalysis; Trifluoromethylation; Heterocycles; Ruthenium
- Citation
- TETRAHEDRON LETTERS, v.53, no.15, pp 2005 - 2008
- Pages
- 4
- Journal Title
- TETRAHEDRON LETTERS
- Volume
- 53
- Number
- 15
- Start Page
- 2005
- End Page
- 2008
- ISSN
- 0040-4039
- Abstract
- A method has been developed for the visible light-induced trifluoromethylation of heterocyclic compounds. A variety of electron-rich heterocycles were transformed into trifluoromethylated products by using CF3I as the trifluoromethyl radical source and Ru(bpy)(3)Cl-2 as the photocatalyst under mild reaction conditions. This operationally simple and eco-friendly process can introduce trifluoromethyl groups without prefunctionalization. (C) 2012 Elsevier Ltd. All rights reserved.
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