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Selectivity in the ruthenium-catalyzed alder ene reactions of di- and triynes
- Authors
- Cho, Eun Jin; Lee, Daesung
- Issue Date
- May-2007
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.129, no.21, pp 6692 - +
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume
- 129
- Number
- 21
- Start Page
- 6692
- End Page
- +
- ISSN
- 0002-7863
1520-5126
- Abstract
- Ruthenium-catalyzed Alder ene reactions between diynes and triynes with terminal alkenes gave the corresponding enynes and enediynes with high regio- and site-selectivity. The selectivity profile clearly indicates that one of the alkynyl moieties of 1,3-diynes not participating in the reaction determines the regiochemistry, whereas the interplay between steric hindrance and polar substituents at the propargylic sites determines the site-selectivity.
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