Detailed Information
Cited 1 time in 
Cited 1 time in 
Cited 1 time in
Metadata Downloads
Fluorometric analysis of borohydrides based on reductive aldehyde-to-alcohol conversion of arylaldehydes
- Authors
- Kim, N.Y.; Baek, J.H.; Chang, Suk-Kyu
- Issue Date
- Jan-2019
- Publisher
- Elsevier Ltd
- Keywords
- Arylaldehyde; Borohydride assay; Aldehyde-to-alcohol reduction; Reaction-based probe; Fluorescent signaling
- Citation
- Tetrahedron Letters, v.60, no.1, pp 59 - 62
- Pages
- 4
- Journal Title
- Tetrahedron Letters
- Volume
- 60
- Number
- 1
- Start Page
- 59
- End Page
- 62
- ISSN
- 0040-4039
- Abstract
- Fluorometric analysis of borohydride (BH4 –) species by the reduction of arylaldehydes to the corresponding arylmethanols was investigated. 9-Anthracenecarboxaldehyde (9-AA) exhibited pronounced ratiometric fluorescence signaling behavior toward borohydride in alkaline aqueous media. The borohydride-selective signaling of 9-AA was unaffected by the presence of commonly encountered metal ions and anions. 1-Pyrenecarboxaldehyde (1-PA) also showed comparable borohydride signaling behavior. The detection limit was found to be 7.4 μM (0.11 ppm) for 9-AA and 15.7 μM (0.23 ppm) for 1-PA. The utility of the probe with μPAD as a convenient tool for the determination of borohydrides was demonstrated. © 2018 Elsevier Ltd
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.