Effect of dysprosium doping on structural and vibrational properties of lead-free (Na0.7K0.3)(0.5)Bi0.5TiO3 ferroelectric ceramics

Abstract

This study describes the effect of Dy3+ doping of lead-free ferroelectric sodium potassium bismuth titanate ((Na0.7K0.3)(0.5)Bi0.5TiO3; NKBT) ceramics on their structural, optical, and vibrational properties. X-ray diffraction and Rietveld refinement analyses revealed that NKBT samples exhibited a rhombohedral perovskite structure belonging to the R3c space group, with the incorporation of Dy3+ resulting in structural parameter change and local atomic structure shift to tetragonal P4mm, as supported by the appearance of new Raman modes. Increased Dy3+ content decreased the NKBT band gap from 3.4 to 3.3 eV, which was ascribed to the introduction of Dy 4f levels between valence and conduction bands. Ferroelectric behavior studies combined with transport measurements explained the unexpected ferroelectric response weakening of Dy3+-modified NKBT by increased leakage current densities.