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The first hydride-Meisenheimer adduct of electron-deficient 3-nitronaphthalimide: application to colorimetric borohydride determination

Authors
Choi, Myung GilKim, Na YeongLee, Yu JeongAhn, SangdooChang, Suk-Kyu
Issue Date
Sep-2019
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.55, no.76, pp 11398 - 11401
Pages
4
Journal Title
CHEMICAL COMMUNICATIONS
Volume
55
Number
76
Start Page
11398
End Page
11401
URI
https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/36977
DOI
10.1039/c9cc05597e
ISSN
1359-7345
1364-548X
Abstract
The first hydride-Meisenheimer adduct of 3-nitronaphthalimide was used for the colorimetric borohydride assay. To explain the regioselectivity of the adduct, the reaction enthalpies of the two most plausible Meisenheimer adducts were obtained via computational calculation. Using the adduct formation, the assay of borohydride reagents was successfully conducted.
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Ahn, Sang Doo
자연과학대학 (화학과)
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