Ordered mesoporous tungsten oxide–carbon nanocomposite for use as a highly reversible negative electrode in lithium-ion batteries
- Authors
- Kim, Hyun-seung; Ryu, Ji Heon; Kim, Jaekwang; Hwang, Keebum; Kang, Hyunchul; Oh, Seoung M; Son, Hyungbin; Yoon, Songhun
- Issue Date
- Aug-2020
- Publisher
- Elsevier Ltd
- Keywords
- Carbon nanocomposites; Lithium-ion batteries; Metal oxides; Negative electrodes; Ordered mesoporous structure
- Citation
- Journal of Alloys and Compounds, v.832
- Journal Title
- Journal of Alloys and Compounds
- Volume
- 832
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/41342
- DOI
- 10.1016/j.jallcom.2020.154816
- ISSN
- 0925-8388
1873-4669
- Abstract
- In the present study, a tungsten oxide–carbon nanocomposite (WOx–C) is synthesized and employed as the negative electrode in lithium-ion batteries. The prepared material exhibited an ordered mesoporous carbon structure uniformly embedded by tungsten oxide nanoparticles. Also, it is composed of about 90% highly reduced tungsten W5+ fraction. The conversion of WOx to W0 and Li2O is proven to be the major lithiation mechanism of WOx–C negative electrode. From electrochemical analysis, a distinct improvement in the delithiation resistance of tungsten oxide within the composite electrode is observed. This improvement in polarization is a result of the high electrical conductivity of the mesoporous carbon matrix and the uniform distribution of tungsten species. The lower delithiation polarization leads to a WOx-C electrode with very stable cycleability, which has been rarely observed in typical conversion-type negative electrodes. © 2020 Elsevier B.V.
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