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Synthesis and electrochemical behavior of a new water soluble Ca2+-selective ionophore based on calix[4]arene-triacid-monoquinone
- Issue Date
- Dec-1998
- Publisher
- CHEMICAL SOC JAPAN
- Citation
- CHEMISTRY LETTERS, no.12, pp 1225 - 1226
- Pages
- 2
- Journal Title
- CHEMISTRY LETTERS
- Number
- 12
- Start Page
- 1225
- End Page
- 1226
- ISSN
- 0366-7022
1348-0715
- Abstract
- A new water-soluble calix[4]arene-triacid-monoquinone 3 has been synthesized and its ion binding properties in aqueous solution were investigated by means of voltammetry and UV-visible spectrophotometry. The electrochemical behavior of 3 is dependent on the concentration of Ca2+ ion rather than that of other alkaline earth metal ions as well as alkali metal cations. The selective response toward Ca2+ was achieved even in the presence of a large excess (> 1000-fold) of interfering Na+ ion.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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