New potassium-selective electrode based on an ionophoric bis(15-crown-5 ether) derived from xanthene-4,5-dicarboxylic acidopen access
- Authors
- Chung, Taek Dong; Chang, Suk-Kyu; Park, Jongseo; Kim, Hasuck
- Issue Date
- 1997
- Publisher
- JAPAN SOC ANALYTICAL CHEM
- Keywords
- bis(15-crown-5 ether); potassium ion-selective electrode; potentiometric analysis
- Citation
- ANALYTICAL SCIENCES, v.13, pp 325 - 328
- Pages
- 4
- Journal Title
- ANALYTICAL SCIENCES
- Volume
- 13
- Start Page
- 325
- End Page
- 328
- URI
- https://scholarworks.bwise.kr/cau/handle/2019.sw.cau/43659
- DOI
- 10.2116/analsci.13.Supplement_325
- ISSN
- 0910-6340
1348-2246
- Abstract
- Bis(15-crown-5 ether) derivatized from a xanthene-4,5-dicarboxylic acid skeleton was studied as an ionophore for a new K+-selective electrode. The polymeric liquid membrane based on this ionophore exhibits Nernstian behavior and optimization of experimental conditions for potentiometric analysis offers a wide linear dynamic range, reasonable detection limit, good durability and hysteresis within a limited error. Due to the well-preorganized structure, the selectivity over Na+ is comparable to those of commercialized K+-selective ionophores and the interferences by some cations such as Rb+ and Cs+ are reduced. Except slightly slow response, the enhanced recognition ability is reminiscent of the natural antibiotic valinomycin.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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