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Thermodynamics of solvent extraction of alkali metal and alkylammonium cations with alkyl calix[6]aryl esters
- Issue Date
- Apr-1995
- Publisher
- GORDON BREACH SCI PUBL LTD
- Citation
- SUPRAMOLECULAR CHEMISTRY, v.4, no.4, pp 315 - 317
- Pages
- 3
- Journal Title
- SUPRAMOLECULAR CHEMISTRY
- Volume
- 4
- Number
- 4
- Start Page
- 315
- End Page
- 317
- ISSN
- 1061-0278
1029-0478
- Abstract
- Alkyl calix[6]aryl esters were found to exhibit significant enthalpy-entropy compensation effect (alpha = 0.92) in solvent extraction of alkali metal and alkylammonium cations. The methyl ester 1 and debutylated ethyl ester 4 showed larger alpha values that might result in inferior binding affinity compared with the ethyl ester 2.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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