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A covalent triazine framework-based heterogenized Al-Co bimetallic catalyst for the ring-expansion carbonylation of epoxide to beta-lactoneopen access
- Issue Date
- 2017
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- RSC ADVANCES, v.7, no.8, pp 4635 - 4638
- Pages
- 4
- Journal Title
- RSC ADVANCES
- Volume
- 7
- Number
- 8
- Start Page
- 4635
- End Page
- 4638
- ISSN
- 2046-2069
- Abstract
- Difficulties in product separation and ineffective recycling of the homogenous catalyst deter the mass production of beta-lactones via carbonylation of epoxides. Herein, we address these issues, for the first time, using a recyclable heterogenized catalyst [bpy-CTF-Al(OTf)(2)][Co(CO)(4)] that efficiently converts propylene oxide (PO) to beta-butyrolactone with high selectivity.
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Collections - College of Natural Sciences > Department of Chemistry > 1. Journal Articles
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